Every shoot starts with four basic questions, are my batteries charged, do I have sufficient card space, what am I shooting and where am I going?
Research is essential for any location. If I'm shooting in a building, park, drainage ditch, alley or any other location that is easily accessible that's one thing, but, If I'm shooting a new location it's always important to research the area as best possible. Once I've familiarized myself with the land, weather, sunrise and sunset of the area, it's time prepare to be spontaneous (don't know how that works but it does).
Once on location I take my time finding the right spot to shoot and generally take mulitple shots from along the way until I find exactly what I'm looking for. Finally, I get to capture that perfect moment.... Geeez what took so long.... I always love watching the environment dance with the light. K, hope this works.
Now for the edit, there are very few photos that I leave completely untouched. My general workflow starts with Adobe Lightroom, where I adjust the RAW images. After Lightroom I export for Photoshop where I finalize the image and prepare versions for web and print.